What are thermoset plastics and why are they so important?

Did you know that some of the most resistant and versatile materials that we use every day cannot be recycled in the same way as other common plastics? Imagine a component that, once molded, maintains its shape even under extreme temperatures. Thermoset plastics play a crucial role in manufacturing high-performance products. From the automotive industry to aeronautics, their ability to withstand adverse conditions makes them an irreplaceable resource. But what makes them so special? 

At Atienza and Climent, as experts in the integral development of products, we know this material and its importance in the industry. If you want to know more about him, keep reading, in this article we will tell you everything.

plásticos termoestgables

What are thermoset plastics?

Thermosets are polymers that, when subjected to an initial heating process, harden irreversibly. This phenomenon occurs thanks to a chemical reaction that forms a cross-linked three-dimensional structure, which gives them great stability. Unlike thermoplastics, which can be molded and remade multiple times, they remain unchanged after their first formation. 

These materials have their origin in synthetic resins developed at the beginning of the 20th century. Their unique chemical structure allows them to withstand high temperatures and stresses without deformation, making them the ideal choice for applications where properties such as heat, wear and chemical resistance are required.

Main properties of thermoset plastics

A thermostable polymer stands out for characteristics that differentiate it from other plastic materials. 

For example:  

High thermal resistance: They can withstand extreme temperatures without melting or deforming. 
Dimensional stability: Once molded, they do not expand or contract significantly. 
Chemical resistance: not affected by most acids, solvents or bases. 
Durability: ideal for products that require a long useful life. 
Electrical insulation: Frequently used in electrical components due to their low conductivity.

plásticos termoestables

Difference between thermosets and thermoplastics

A thermoset and thermoplastic differ mainly in their behavior against heat and their internal structure. The former, once molded and hardened, cannot be melted or reformed, since their reticulated structure provides them with permanent rigidity. On the other hand, the latter have a linear or branched structure that allows them to be cast and molded repeatedly, which makes them more flexible and recyclable.  

While some are used in high-performance applications where thermal and chemical resistance is required, the others are more common in everyday products thanks to their versatility and ease of reprocessing.

Types of thermoset plastics

There are two types of thermosets that are classified according to their chemical composition and end use.

Thermosetting resins: what they are and what they are used for

A thermosetting resin is a chemical compound that, when heated and mixed with a hardening agent, forms a solid, resistant material. They are essential in the manufacture of coatings, adhesives and composite materials such as fiberglass. Some common examples include epoxy resins and polyester resins.

Thermostable elastomers: characteristics and uses

Thermoset elastomers combine the flexibility of rubber with the durability of a thermoset plastic. They are used in gaskets, seals and molded parts, as they are resistant to permanent deformation even after long periods of use.

Examples of thermoset plastics

Among the thermostable materials, epoxy resins, polyurethanes and phenolics stand out. These are used to make electrical switches, automobile components, and heat-resistant kitchen utensils.

Industrial sectors where they are most used

The examples of thermosets in the industry are countless. These are some of the sectors where they are most frequently used due to the properties they contain:

  1. Aeronautics 

    In this sector, they are essential due to their lightness, thermal resistance and ability to withstand high stresses. They are used in the manufacture of structural components, interior panels and housings of electronic systems, helping to reduce the weight of aircraft and, therefore, fuel consumption.

  1. Automotive 

    The automotive industry uses them in parts such as engine casings, brake system components, and heat- and chemical-resistant coatings. Its use guarantees a long useful life, in addition to meeting the demands of sustainability and performance.

  2. Electronic and electrical 

    This sector uses them to manufacture device casings, insulators and printed circuits. Their electrical insulation capacity and high temperature resistance make them the best option for products such as household appliances, industrial equipment and electronic gadgets. 

    Construction and architecture 

    Structural adhesives, protective coatings and decorative panels made of these plastics are essential in construction projects. They offer durability against the elements and resistance to corrosive agents, ensuring more robust and low-maintenance structures.

  1. medical sector 

    In the hospital setting, they are found in medical devices, prostheses and laboratory elements. Their resistance to sterilization processes and their biocompatibility make them ideal for meeting the most demanding health standards.

  2. Renewable energy 

    In technologies such as wind and solar, they are used in wind turbine blades and solar panel casings. Their durability and resistance to extreme weather conditions contribute to the long-term performance of these sustainable energy sources.

Advantages over other plastic materials 

Thermoset is a material that stands out for offering key advantages over other plastics, especially in the most demanding industries. Their ability to withstand extreme temperatures without deforming makes them ideal for sectors such as automotive and aeronautics. 

In addition, its chemical stability ensures resistance to acids, solvents and corrosive agents, which expands its usefulness in industrial and medical environments. Unlike other heavier materials, they combine lightness with high mechanical resistance, allowing robust and efficient structures.  

They also stand out for their excellent electrical insulation capacity, being essential in electronic and electrical components. These features make them a reliable and high-performance option.

Benefits of thermoset plastics

These materials have complementary uses, but the benefits of thermosets make them stand out in demanding applications. Among its main advantages we can highlight:

  • Sustainability in industrial applications: Despite not being conventionally recyclable, their long useful life reduces the need for frequent replacement, minimizing long-term environmental impact. 
    Customization capabilities: They can accommodate a wide range of specific needs, from small, complex parts to large structural components. 
    Performance in extreme conditions: withstand harsh environments, including high temperatures, humidity and exposure to harsh chemicals. 
    Reliability in critical sectors: their stability and reliability make them a key material for industries such as aeronautics, automotive and medical, where quality and safety are paramount. 
    Combined aesthetics and functionality: in sectors such as architecture and design, they not only offer resistance, but also visually attractive finishes. 

    In short, these are very versatile materials that guarantee results of maximum quality and resistance in demanding sectors. At Atienza y Climent, we work with thermostables and thermoplastics to turn any idea into a reality.

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